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Hey Agron1000,

 

In order to get another chance of catching it you need to beat Boss Horon in Dark Valley. And I would recommend getting a Masterball and using it for Darkrai this time 🙂

 

You can get Masterballs with PVE Coins (you get from Bosses, Battle Tower, Bug catching contest or from giving event form Pokes /Shinys to Joron in any department store).

 

I hope that helped and please let me know if you got any more questions.

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Hail to the ANT KING

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