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Hello @Mvnschaalke,

 

It seems that the evolution process was conducted during the incorrect time, as Riolu evolves into Lucario when it attains maximum happiness during daytime (10:00 - 20:00 in-game time). As you mentioned, since the procedure took place at night-time, the evolution did not occur.

 

To trigger Riolu's evolution, faint it in a wild battle once again and maximize its happiness during daytime. This should ideally prompt the evolution. There shouldn't be any need of using Mysterious Candy in happiness evolutions.

In the event that the evolution still does not occur despite following these steps correctly, we recommend repeating the procedure with the help of Pokemon Groomer or Pokemon Cafe NPCs this time for increasing the Pokemon's happiness. NPC Brad and Chris can be found in the following locations:

  • Kanto - Cerulean City House 5
  • Johto - Goldenrod Underground Path
  • Hoenn - Slateport City
  • Sinnoh - Hearthome City

Please let us know of the outcome after completing these steps. We will be waiting for your response.

 

Kind regards,

Yverneas

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