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Hi. Thank you for contacting us about your issue.

 

Indeed, as @Mysticwind kindly pointed out, Toxic used by a Poison-type Pokémon will guarantee to hit the opposite Pokémon even if they're in a semi-invulnerable state (Fly, Dig, even Phantom Force I believe). If your Pokémon is a Steel or Poison type, it won't get poisoned obviously. This has been the case since Generation IV.

 

We hope the information provided will be useful to you. Do not shy away to come back and ask if you have any future questions. Good luck in your adventures!

 

- Kubrick

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