Hello mccloudzz,
To try solve this crash issue, create a new folder on your desktop and extract all of the files into the new folder. Right click on the PRO executable and run it as admin.
If that doesn't work, try out these guides:
https://pokemonrevolution.net/forum/viewtopic.php?f=16&t=14688
https://pokemonrevolution.net/forum/viewtopic.php?f=16&t=31177
https://pokemonrevolution.net/forum/viewtopic.php?f=16&t=14738